Hybrid Chlorides with Methylhydrazinium Cation: [CH₃NH₂NH₂]CdCl₃ and Jahn-Teller Distorted [CH₃NH₂NH₂]CuCl₃.

ABSTRACT: The synthesis, structural, phonon, optical, and magnetic properties of two hybrid organic-inorganic chlorides with monoprotonated methylhydrazinium cations (CH₃NH₂NH₂⁺, MHy⁺), [CH₃NH₂NH₂]CdCl₃ (MHyCdCl₃), and [CH₃NH₂NH₂]CuCl₃ (MHyCuCl₃), are reported. In contrast to previously reported MHyM^IICl₃ (M^II = Mn²⁺, Ni²⁺, and Co²⁺) analogues, neither compound undergoes phase transitions. The MHyCuCl₃ has a crystal structure familiar to previous crystals composed of edge-shared 1D chains of the [CuCl₅N] octahedra. MHyCuCl₃ cr

SUBMITTER: Zienkiewicz JA 

PROVIDER: S-EPMC9865361 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature