Enhanced Electrochemical Performance of PEO-Based Composite Polymer Electrolyte with Single-Ion Conducting Polymer Grafted SiO₂ Nanoparticles.

ABSTRACT: In order to enhance the electrochemical performance and mechanical properties of poly(ethylene oxide) (PEO)-based solid polymer electrolytes, composite solid electrolytes (CSE) composed of single-ion conducting polymer-modified SiO₂, PEO and lithium salt were prepared and used in lithium-ion batteries in this work. The pyridyl disulfide terminated polymer (py-ss-PLiSSPSI) is synthesized through RAFT polymerization, then grafted onto SiO₂ via thiol-disulfide exchange reaction between SiO₂-SH and py-ss-PLiSSPSI. The chemical structure, surface morphology and elemental distribution of the as-prepared polymer and the PLiSSPSI-g-SiO₂ nanoparticles have been investigated. Moreover, CSEs containing 2, 6, and 10 wt% PLiSSPSI-g-SiO₂

SUBMITTER: Liu X 

PROVIDER: S-EPMC9866075 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature