Synthesis, Optical Properties, and Fluorescence Cell Imaging of Novel Mixed Fluorinated Subphthalocyanines.

ABSTRACT: Subphthalocyanines (SubPcs) are a kind of tripyrrolic macrocycle with a boron atom at their core. Incorporating different units onto the SubPc periphery can endow them with various unique properties. Herein, a series of novel fluorinated low-symmetry SubPc derivatives containing chlorine groups (F₈-Cl₄-SubPc, F₄-Cl₈-SubPc) and methoxy groups (F₈-(OCH₃)₂-SubPc) were synthesized and characterized by spectral methods (MS, FT-IR, ¹H, ¹³C, ¹¹B, and ¹⁹F NMR spectroscopy), and the effect of the peripheral substituents on their electronic structure of low-symmetry macrocycle was investigated by cyclic voltammetry, theoretical calculation, electronic absorption, and emission spec

SUBMITTER: Zhou S 

PROVIDER: S-EPMC9866271 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature