An Experimental and Master Equation Investigation of Kinetics of the CH₂OO + RCN Reactions (R = H, CH₃, C₂H₅) and Their Atmospheric Relevance.

ABSTRACT: We have performed direct kinetic measurements of the CH₂OO + RCN reactions (R = H, CH₃, C₂H₅) in the temperature range 233-360 K and pressure range 10-250 Torr using time-resolved UV-absorption spectroscopy. We have utilized a new photolytic precursor, chloroiodomethane (CH₂ICl), whose photolysis at 193 nm in the presence of O₂ produces CH₂OO. Observed bimolecular rate coefficients for CH₂OO + HCN, CH₂OO + CH₃CN, and CH₂OO + C₂H₅CN reactions at 296 K are (2.22 ± 0.65) × 10^-14 cm³ molecule^-1 s^-1, (1.02 ± 0.10) × 10^-14 cm³ molecule^-1 s^-1, and (2.55 ± 0.13) × 10

SUBMITTER: Franzon L 

PROVIDER: S-EPMC9869398 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature