Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand.

ABSTRACT: The synthesis and iridium coordination chemistry of a new pyridine-based phosphinito pincer ligand 2,6-(Ar^F₂PO)₂C₅H₃N (PONOP-Ar^F; Ar^F = 2-(CF₃)C₆H₄) are described, where the P-donors have ortho-trifluoromethylphenyl substituents. The iridium(III) 2,2'-biphenyl (biph) derivative [Ir(PONOP-Ar^F)(biph)Cl] was obtained by reaction with [Ir(biph)(COD)Cl]₂ (COD = 1,5-cyclooctadiene) and subsequent halide ion abstraction enabled isolation of [Ir(PONOP-Ar^F)(biph)]⁺ which features an Ir ← F-C bonding interaction in the solid state. Hydrogenolysis of the biphenyl ligand and formation of [Ir(PONOP-Ar^F)(H)₂]⁺ wa

SUBMITTER: Poole EW 

PROVIDER: S-EPMC9872493 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature