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[EMmim][NTf2 ]-a Novel Ionic Liquid (IL) in Catalytic CO2 Capture and ILs' Applications.


ABSTRACT: Ionic liquids (ILs) have been used for carbon dioxide (CO2 ) capture, however, which have never been used as catalysts to accelerate CO2 capture. The record is broken by a uniquely designed IL, [EMmim][NTf2 ]. The IL can universally catalyze both CO2 sorption and desorption of all the chemisorption-based technologies. As demonstrated in monoethanolamine (MEA) based CO2 capture, even with the addition of only 2000 ppm IL catalyst, the rate of CO2 desorption-the key to reducing the overall CO2 capture energy consumption or breaking the bottleneck of the state-of-the-art technologies and Paris Agreement implementation-can be increased by 791% at 85 °C, which makes use of low-temperature waste heat and avoids secondary pollution during CO2 capture feasible. Furthermore, the catalytic CO2 capture mechanism is experimentally and theoretically revealed.

SUBMITTER: He X 

PROVIDER: S-EPMC9875647 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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[EMmim][NTf<sub>2</sub> ]-a Novel Ionic Liquid (IL) in Catalytic CO<sub>2</sub> Capture and ILs' Applications.

He Xin X   Gao Yangyan Y   Shi Yunlei Y   Zhang Xiaowen X   Liang Zhiwu Z   Zhang Riguang R   Song Xingfei X   Lai Qinghua Q   Adidharma Hertanto H   Russell Armistead G AG   Eddings Eric G EG   Fei Weiyang W   Cheng Fangqin F   Tsang Shik Chi Edman SCE   Wang Jianji J   Fan Maohong M  

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20221123 3


Ionic liquids (ILs) have been used for carbon dioxide (CO<sub>2</sub> ) capture, however, which have never been used as catalysts to accelerate CO<sub>2</sub> capture. The record is broken by a uniquely designed IL, [EMmim][NTf<sub>2</sub> ]. The IL can universally catalyze both CO<sub>2</sub> sorption and desorption of all the chemisorption-based technologies. As demonstrated in monoethanolamine (MEA) based CO<sub>2</sub> capture, even with the addition of only 2000 ppm IL catalyst, the rate of  ...[more]

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