A zinc-conducting chalcogenide electrolyte.

ABSTRACT: A solid-state zinc-ion battery can fundamentally eliminate dendrite formation and hydrogen evolution on the zinc anode from aqueous systems. However, enabling fast zinc ion ⁺ conduction in solid crystals is thought to be impossible. Here, we demonstrated a fluorine-doping approach to achieving fast Zn²⁺ transport in mesoporous Zn_yS_1-xF_x. The substitutional doping of fluoride ion with sulfide substantially reduces Zn²⁺ migration barrier in a crystalline phase, while mesopore channels with bounded dimethylformamide enable nondestructive Zn²⁺ conduction along inner pore surface. This mesoporous conductor features a high room-temperature Zn²⁺ conductivity (0.66 millisiemens per centimet

SUBMITTER: Zhi J 

PROVIDER: S-EPMC9882973 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature