Dataset Information

Bimetallic FeO _x -MO _x Loaded TiO₂ (M = Cu, Co) Nanocomposite Photocatalysts for Complete Mineralization of Herbicides.

ABSTRACT: A series of monometallic and bimetallic cocatalyst(s), comprising FeO _x , CuO _x , CoO _x , FeO _x -CuO _x , and FeO _x -CoO _x loaded TiO₂ catalysts prepared by the surface impregnation method, were investigated for the photocatalytic mineralization of the widely used four herbicides: 2,4-dichlorophenol (2,4-DCP), 2,4,6-trichlorophenol (2,4,6-TCP), 2,4-dichlorophenoxyacetic acid (2,4-D), and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T). It was found that FeO _x -CoO _x /TiO₂ showed the highest photocatalytic efficiency toward mineralization of selected herbicides. FeO _x -CoO _x /TiO₂ achieves 92% TOC removal in 180 min, representing nearly three time activity of the benchmark PC50 TiO₂. From XPS analysis, FeOOH, CuO, and CoO were determined to be loaded onto the TiO₂ surface. The outstanding photocatalytic performance of the optimized FeO _x -CoO _x /TiO₂ sample for herbicides mineralization is due to an increased charge separation and enhanced hydroxyl radicals production monitored by diverse spectroscopies. Based on the proposed charge transfer mechanism, FeO _x -CoO _x cocatalyst species accelerate the transfer of photogenerated holes on TiO₂, thus facilitating hydroxyl radicals production.

SUBMITTER: Shoneye A

PROVIDER: S-EPMC9884081 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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Publications

Bimetallic FeO x -MO x Loaded TiO2 (M = Cu, Co) Nanocomposite Photocatalysts for Complete Mineralization of Herbicides.

Shoneye Ayoola A Jiao Haimiao H Tang Junwang J

The journal of physical chemistry. C, Nanomaterials and interfaces 20230117 3

A series of monometallic and bimetallic cocatalyst(s), comprising FeO x , CuO x , CoO x , FeO x -CuO x , and FeO x -CoO x loaded TiO2 catalysts prepared by the surface impregnation method, were investigated for the photocatalytic mineralization of the widely used four herbicides: 2,4-dichlorophenol (2,4-DCP), 2,4,6-trichlorophenol (2,4,6-TCP), 2,4-dichloropheno ...[more]

PMID: 36721769

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Project description:Water scarcity is now a serious global issue resulting from population growth, water decrease, and pollution. Traditional wastewater treatment plants are insufficient and cannot meet the basic standards of water quality at reasonable cost or processing time. In this paper we report the preparation, characterization and multiple applications of an efficient photocatalytic nanocomposite (CoxNi1-xFe2O4; x = 0.9/SiO2/TiO2/C-dots) synthesized by a layer-by-layer method. Then, the photocatalytic capabilities of the synthesized nanocomposite were extensively-studied against aqueous solutions of chloramine-T trihydrate. In addition, reaction kinetics, degradation mechanism and various parameters affecting the photocatalytic efficiency (nanocomposite dose, chloramine-T initial concentration, and reaction pH) were analyzed in detail. Further, the antimicrobial activities of the prepared nanocomposite were tested and the effect of UV-activation on the antimicrobial abilities of the prepared nanocomposite was analyzed. Finally, a comparison between the antimicrobial abilities of the current nanocomposite and our previously-reported nanocomposite (CoxNi1-xFe2O4; x = 0.9/SiO2/TiO2) had been carried out. Our results revealed that the prepared nanocomposite possessed a high degree of crystallinity, confirmed by XRD, while UV-Vis. recorded an absorption peak at 299 nm. In addition, the prepared nanocomposite possessed BET-surface area of (28.29 ± 0.19 m2/g) with narrow pore size distribution. Moreover, it had semi-spherical morphology, high-purity and an average particle size of (19.0 nm). The photocatalytic degradation efficiency was inversely-proportional to chloramine-T initial concentration and directly proportional to the photocatalyst dose. In addition, basic medium (pH 9) was the best suited for chloramine-T degradation. Moreover, UV-irradiation improved the antimicrobial abilities of the prepared nanocomposite against E. coli, B. cereus, and C. tropicalis after 60 min. The observed antimicrobial abilities (high ZOI, low MIC and more efficient antibiofilm capabilities) were unique compared to our previously-reported nanocomposite. Our work offers significant insights into more efficient water treatment and fosters the ongoing efforts looking at how pollutants degrade the water supply and the disinfection of water-borne pathogenic microorganisms.

Dataset Information

Bimetallic FeO _x -MO _x Loaded TiO₂ (M = Cu, Co) Nanocomposite Photocatalysts for Complete Mineralization of Herbicides.

Publications

Bimetallic FeO <sub><i>x</i></sub> -MO <sub><i>x</i></sub> Loaded TiO<sub>2</sub> (M = Cu, Co) Nanocomposite Photocatalysts for Complete Mineralization of Herbicides.

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