Carbon Nanotube PtSn Nanoparticles for Enhanced Complete Biocatalytic Oxidation of Ethylene Glycol in Biofuel Cells.

ABSTRACT: We report a hybrid catalytic system containing metallic PtSn nanoparticles deposited on multiwalled carbon nanotubes (Pt₆₅Sn₃₅/MWCNTs), prepared by the microwave-assisted method, coupled to the enzyme oxalate oxidase (OxOx) for complete ethylene glycol (EG) electrooxidation. Pt₆₅Sn₃₅/MWCNTs, without OxOx, showed good electrochemical activity toward EG oxidation and all the byproducts. Pt₆₅Sn₃₅/MWCNTs cleaved the glyoxilic acid C-C bond, producing CO₂ and formic acid, which was further oxidized at the electrode. Concerning EG oxidation, the catalytic activity of the hybrid system (Pt₆₅Sn₃₅/MWCNTs+OxOx) was twice the catalytic activity of Pt₆₅Sn₃₅/MWCNTs. Long-term electro

SUBMITTER: Antonio JGR 

PROVIDER: S-EPMC9888613 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature