Back to the future: asymmetrical DπA 2,2′-bipyridine ligands for homoleptic copper(i)-based dyes in dye-sensitised solar cells† † Electronic supplementary information (ESI) available: Experimental section. Fig. S1–S45; NMR spectra; Fig. S46–S60: FT-IR spectra; HR-MS spectra: S61–S75; Table S1: DOSY data; Fig. S76: cyclic voltammograms; Fig. S77, S78 and Table S2: DFT calculations; J–V parameters: Tables S3–S8. CCDC 2203243. For ESI and crystallographic data in CIF or other electronic format see DOI: https://doi.org/10.1039/d3ra00437f

ABSTRACT: Metal complexes used as sensitisers in dye-sensitised solar cells (DSCs) are conventionally constructed using a push–pull strategy with electron-releasing and electron-withdrawing (anchoring) ligands. In a new paradigm we have designed new DπA ligands incorporating diarylaminophenyl donor substituents and phosphonic acid anchoring groups. These new ligands function as organic dyes. For two separate classes of DπA ligands with 2,2′-bipyridine metal-binding domains, the DSCs containing the copper(i) complexes [Cu(DπA)2]+ perform better than the push–pull analogues [Cu(DD)(AA)]+. Furthermore, we have shown for the first time that the complexes [Cu(DπA)2]+ perform better than the organic DπA dye in DSCs. The synthetic studies and the device performances are rationalised with the aid of density

SUBMITTER: Risi G 

PROVIDER: S-EPMC9890583 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature