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New iron(iii) complex of bis-bidentate-anchored diacyl resorcinol on a Fe₃O₄ nanomagnet: C-H bond oxygenation, oxidative cleavage of alkenes and benzoxazole synthesis.

ABSTRACT: We have synthesized a novel, bis-bidentate, covalently anchored, 4,6-diacetyl resorcinol (DAR) ligand on silica-coated magnetic Fe₃O₄ nanoparticles and the corresponding bi-metallic iron(iii) complex (Fe₃O₄@SiO₂-APTESFe₂L^DAR). Both the chemical nature and the structure of the homogeneously heterogenized catalyst were investigated using physico-chemical techniques. The results obtained by XPS, XRD, FT-IR, TGA, VSM, SEM, TEM, EDX, ICP and AAS revealed a magnetic core, a silica layer and the grafting of a binuclear iron complex on the Fe₃O₄@SiO₂-APTES, as well as its thermodynamic stability. Despite many reports of metal complexes on different supports, there are no reports of anchore

SUBMITTER: Majedi M

PROVIDER: S-EPMC9890640 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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New iron(iii) complex of bis-bidentate-anchored diacyl resorcinol on a Fe₃O₄ nanomagnet: C-H bond oxygenation, oxidative cleavage of alkenes and benzoxazole synthesis.

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New iron(iii) complex of bis-bidentate-anchored diacyl resorcinol on a Fe3O4 nanomagnet: C-H bond oxygenation, oxidative cleavage of alkenes and benzoxazole synthesis.

OmicsDI is part of the ELIXIR infrastructure

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New iron(iii) complex of bis-bidentate-anchored diacyl resorcinol on a Fe₃O₄ nanomagnet: C-H bond oxygenation, oxidative cleavage of alkenes and benzoxazole synthesis.