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A comprehensive review on the electrochemical parameters and recent material development of electrochemical water splitting electrocatalysts.

ABSTRACT: Electrochemical splitting of water is an appealing solution for energy storage and conversion to overcome the reliance on depleting fossil fuel reserves and prevent severe deterioration of the global climate. Though there are several fuel cells, hydrogen (H₂) and oxygen (O₂) fuel cells have zero carbon emissions, and water is the only by-product. Countless researchers worldwide are working on the fundamentals, i.e. the parameters affecting the electrocatalysis of water splitting and electrocatalysts that could improve the performance of the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) and overall simplify the water electrolysis process. Noble metals like platinum for HER and ruthenium and iridium for OER were used earlier; however, being expensive, there are more feasible options than employing these metals for all commercialization. The review discusses the recent developments in metal and metalloid HER and OER electrocatalysts from the s, p and d block elements. The evaluation perspectives for electrocatalysts of electrochemical water splitting are also highlighted.

SUBMITTER: Raveendran A

PROVIDER: S-EPMC9890951 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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A comprehensive review on the electrochemical parameters and recent material development of electrochemical water splitting electrocatalysts.

Raveendran Asha A Chandran Mijun M Dhanusuraman Ragupathy R

RSC advances 20230126 6

Electrochemical splitting of water is an appealing solution for energy storage and conversion to overcome the reliance on depleting fossil fuel reserves and prevent severe deterioration of the global climate. Though there are several fuel cells, hydrogen (H2) and oxygen (O2) fuel cells have zero carbon emissions, and water is the only by-product. Countless researchers worldwide are working on the fundamentals, i.e. the parameters affecting the electrocatalysis of wat ...[more]

PMID: 36756592

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Project description:The security of future energy, hydrogen, is subject to designing high-performance, stable, and low-cost electrocatalysts for hydrogen and oxygen evolution reactions (HERs and OERs), for the realization of efficient overall water splitting. Two-dimensional (2D) metal-organic frameworks (MOFs) introduce a large family of materials with versatile chemical and structural features for a variety of applications, such as supercapacitors, gas storage, and water splitting. Herein, a series of nanocomposites based on NCM/Ni-BDC@NF (N=Ni, C=Co, M:F=Fe, C=Cu, and Z=Zn, BDC: benzene dicarboxylic acid, NF: nickel foam) were directly developed on NF using a facile yet scalable solvothermal method. After coupling, the electronic structure of metallic atoms was well-modulated. Based on the XPS results, for the NCF/Ni-BDC, cationic atoms shifted to higher oxidation states, favorable for the OER. Conversely, for the NCZ/Ni-BDC and NCC/Ni-BDC nanocomposites, cationic atoms shifted to lower oxidation states, advantageous for the HER. The as-prepared NCF/Ni-BDC demonstrated prominent OER performance, requiring only 1.35 and 1.68 V versus a reversible hydrogen electrode to afford 10 and 50 mA cm-2 current densities, respectively. On the cathodic side, NCZ/Ni-BDC exhibited the best HER activity with an overpotential of 170 and 350 mV to generate 10 and 50 mA cm-2, respectively, under 1.0 M KOH medium. In a two-electrode alkaline electrolyzer, the assembled NCZ/Ni-BDC (cathode) ∥ NCF/Ni-BDC (anode) couple demanded a cell voltage of only 1.58 V to produce 10 mA cm-2. The stability of NCF/Ni-BDC toward OER was also exemplary, experiencing a continuous operation at 10, 20, and 50 mA cm-2 for nearly 45 h. Surprisingly, the overpotential after OER stability at 50 mA cm-2 dropped drastically from 450 to 200 mV. Finally, the faradaic efficiencies for the overall water splitting revealed the respective values of 100 and 85% for the H2 and O2 production at a constant current density of 20 mA cm-2.

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A comprehensive review on the electrochemical parameters and recent material development of electrochemical water splitting electrocatalysts.

Publications

A comprehensive review on the electrochemical parameters and recent material development of electrochemical water splitting electrocatalysts.

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