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Branching phenomena in nanostructure synthesis illuminated by the study of Ni-based nanocomposites.


ABSTRACT: Branching phenomena are ubiquitous in both natural and artificial crystallization processes. The branched nanostructures' emergent properties depend upon their structures, but their structural tunability is limited by an inadequate understanding of their formation mechanisms. Here we developed an ensemble of Nickel-Based nano-Composites (NBCs) to investigate branching phenomena in solution-phase synthesis with precision and in depth. NBCs of 24 morphologies, including dots, core@shell dots, hollow shells, clusters, polyhedra, platelets, dendrites, urchins, and dandelions, were synthesized through systematic adjustment of multiple synthesis parameters. Relationships between the synthesis parameters and the resultant morphologies were analyzed. Classical or non-classical models of nucleation

SUBMITTER: Qiao L 

PROVIDER: S-EPMC9891374 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature