Photoluminescence of the Au₃₈(SR)₂₆ nanocluster comprises three radiative processes.

ABSTRACT: Photoluminescence of ultrasmall, atomically precise gold nanoclusters constitutes an area of significant interest in recent years for both fundamental research and biological applications. However, the exploration of near-infrared photoluminescence of gold nanoclusters is still in its infancy due to the limitations of synthetic methods and characterization techniques. Herein, the photoluminescence properties of an Au₃₈(PET)₂₆ (PET = 2-phenylethanethiolate) nanocluster are investigated in detail. The Au₃₈(PET)₂₆ exhibits an emission peak at 865 nm, which is revealed to be a mix of fluorescence, thermally activated delayed fluorescence, and phosphorescence via the combined analyses of time-resolved and temperature-dependent photoluminescence measurements. The quantum yield of Au₃₈(PET)₂₆ is determined to be 1.8% at room temperature under ambient conditions, which increases to above 90% by suppressing the non-radiative relaxation pathway at a cryogenic temperature (80 K). Overall, the results of this work discover the coexistence of three radiative processes in thiolate-protected Au nanoclusters and will pave the way for understanding the intriguing photoluminescence properties of gold nanoclusters in future studies.

SUBMITTER: Luo L 

PROVIDER: S-EPMC9894927 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature