Reactivity and Structure of a Bis-phenolate Niobium NHC Complex.

ABSTRACT: We report the facile synthesis of a rare niobium(V) imido NHC complex with a dianionic OCO-pincer benzimidazolylidene ligand (L ¹ ) with the general formula [NbL ¹ (N ^t Bu)PyCl] 1-Py. We achieved this by in situ deprotonation of the corresponding azolium salt [H ₃ L ¹ ][Cl] and subsequent reaction with [Nb(N ^t Bu)Py ₂ Cl ₃ ]. The pyridine ligand in 1-Py can be removed by the addition of B(C₆F₅)₃ as a strong Lewis acid leading to the formation of the pyridine-free complex 1. In contrast to similar vanadiu

SUBMITTER: Neururer FR 

PROVIDER: S-EPMC9896488 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature