Soluble Diphenylhexatriene Dimers for Intramolecular Singlet Fission with High Triplet Energy.

ABSTRACT: Intramolecular singlet fission (iSF) facilitates single-molecule exciton multiplication, converting an excited singlet state to a pair of triplet states within a single molecule. A critical parameter in determining the feasibility of SF-enhanced photovoltaic designs is the triplet energy; many existing iSF materials have triplet energies too low for efficient transfer to silicon via a photon multiplier scheme. In this work, a series of six novel dimers based upon the high-triplet-energy, SF-active chromophore, 1,6-diphenyl-1,3,5-hexatriene (DPH) [E(T₁) ∼ 1.5 eV], were designed, synthesized, and characterized. Transient absorption spectroscopy and fluorescence lifetime studies reveal that five of the dimers display iSF activity, with time constants for singlet fission vary

SUBMITTER: Millington O 

PROVIDER: S-EPMC9896565 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature