Achieving giant electrostrain of above 1% in (Bi,Na)TiO₃-based lead-free piezoelectrics via introducing oxygen-defect composition.

ABSTRACT: Piezoelectric ceramics have been extensively used in actuators, where the magnitude of electrostrain is key indicator for large-stroke actuation applications. Here, we propose an innovative strategy based on defect chemistry to form a defect-engineered morphotropic phase boundary and achieve a giant strain of 1.12% in lead-free Bi_0.5Na_0.5TiO₃ (BNT)-based ceramics. The incorporation of the hypothetical perovskite BaAlO_2.5 with nominal oxygen defect into BNT will form strongly polarized directional defect dipoles, leading to a strong pinning effect after aging. The large asymmetrical strain is mainly attributed to two factors: The defect dipoles along crystallographic [001] direction destroy the long-range ordering of the ferroelectric and activate a reversible phase transition while promoting polarization rotation when the dipoles are aligned along the applied electric field. Our results not only demonstrate the potential application of BNT-based materials in low-frequency, large-stroke actuators but also provide a general methodology to achieve large strain.

SUBMITTER: Luo H 

PROVIDER: S-EPMC9897659 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature