Topological dual and extended relations between networks of clathrate hydrates and Frank-Kasper phases.

ABSTRACT: Clathrate hydrates are a class of ordered structures that are stabilized via the delicate balance of hydrophobic interactions between water and guest molecules, of which the space-filling network of hydrogen-bonded (H-bonded) water molecules are closely related to tetrahedrally close-packed structures, known as Frank-Kasper (FK) phases. Here we report an alternative way to understand the intricate structures of clathrate hydrates, which unveils the diverse crystalline H-bonded networks that can be generated via assembly of one common building block. In addition to the intrinsic relations and pathways linking these crystals, we further illustrate the rich structural possibilities of clathrate hydrates. Given that the topological dual relations between networks of clathrate hydrates and tetr

SUBMITTER: Chen Y 

PROVIDER: S-EPMC9898525 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature