Stabilization of copper nanoparticles onto the double Schiff-base-functionalized ZSM-5 for A³ coupling reaction catalysis aimed under mild conditions.

ABSTRACT: In this research a highly efficient and heterogeneous catalyst of ZSM-5@APTMS@(E)-4-((pyridin-2-ylimino)methyl) benzaldehyde@Cu-NPs was synthesized for upgrading the A³ coupling reaction for the synthesis of propargylamines under mild conditions. Rational tuning of the microenvironment of metallic NPs to improve efficiency and reusability in catalytic performances is of significance for scalable applications. Firstly, ZSM-5 was immobilized with APTMS (3-aminopropyltrimethoxysilane) and further modified with (E)-4-((pyridin-2-ylimino)methyl)benzaldehyde. Subsequently, the amine-activated zeolite@(E)-4-((pyridin-2-ylimino)methyl)benzaldehyde was applied to increase the stabilization of Cu metal nanoparticles. The catalyst was treated with hydrazine to reduce C

SUBMITTER: Mohammadi L 

PROVIDER: S-EPMC9903180 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature