A Pyridyl-1,2-azaborine Ligand for Phosphorescent Neutral Iridium(III) Complexes.

ABSTRACT: A novel 1,2-azaborine (i.e., 4-methyl-2-(pyridin-2-yl)-2,1-borazaronaphthalene, 1a) has been synthesized and used for the first time as a B-N alternative to common cyclometalating ligands to obtain neutral phosphorescent iridium(III) complexes (i.e., 2a, 3, and 4) of general formula [Ir(C^∧N)₂(N^∧NB)], where C^∧N indicates three different cyclometalating ligands (Hppy = 2-phenylpyridine; Hdfppy = 2-(2,4-difluoro-phenyl)pyridine; Hpqu = 2-methyl-3-phenylquinoxaline). Moreover, the azaborine-based complex 2a was compared to the isoelectronic C═C iridium(III) complex 2b, obtained using the corresponding 2-(naphthalen-2-yl)pyridine ligand 1b. Due to the dual cyclometalation mode of such C═C

SUBMITTER: Baschieri A 

PROVIDER: S-EPMC9906742 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature