One-pot cascade construction of nonsubstituted quinoline-bridged covalent organic frameworks.

ABSTRACT: Irreversible locking of imine linkages into stable linkages represents a promising strategy to improve the robustness and functionality of covalent organic frameworks (COFs). We report, for the first time, a multi-component one-pot reaction (OPR) for imine annulation to construct highly stable nonsubstituted quinoline-bridged COFs (NQ-COFs), and that equilibrium regulation of reversible/irreversible cascade reactions by addition of MgSO₄ desiccant is crucial to achieve high conversion efficiency and crystallinity. The higher long-range order and surface area of NQ-COFs synthesized by this OPR than those of the reported two-step post-synthetic modification (PSM) facilitate charge carrier transfer and photogeneration ability of superoxide radicals (O₂˙^-), whi

SUBMITTER: Pang H 

PROVIDER: S-EPMC9906769 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature