Chemical Recycling of Polyurethane Waste via a Microwave-Assisted Glycolysis Process.

ABSTRACT: In this work, we explored a microwave-assisted glycolysis process to chemically recycle rigid polyurethane (PU) foam waste to obtain a single-phase product with suitable physio-chemical properties as a secondary raw material for the preparation of new rigid PU products. Such an approach was compared to a conventionally heated (ConvH) process, analyzing the performances of different catalysts. The use of microwaves allowed a 94% decrease in the reaction time scale of rigid PU depolymerization, with a concurrent 45% reduction in energy expense. By using a PU/diethylene glycol mass ratio of 1.5, best performances were obtained with a 30 mmol/100g_PU potassium acetate concentration, both in terms of the product viscosity and aromatic amine byproduct content. The glycolysis products r

SUBMITTER: Donadini R 

PROVIDER: S-EPMC9909786 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature