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Signatures of Room-Temperature Quantum Interference in Molecular Junctions.


ABSTRACT: ConspectusDuring the past decade or so, research groups around the globe have sought to answer the question: "How does electricity flow through single molecules?" In seeking the answer to this question, a series of joint theory and experimental studies have demonstrated that electrons passing through single-molecule junctions exhibit exquisite quantum interference (QI) effects, which have no classical analogues in conventional circuits. These signatures of QI appear even at room temperature and can be described by simple quantum circuit rules and a rather intuitive magic ratio theory. The latter describes the effect of varying the connectivity of electrodes to a molecular core and how electrical conductance can be controlled by the addition of heteroatoms to molecular cores. The former des

SUBMITTER: Liu SX 

PROVIDER: S-EPMC9910048 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature