Structure-Stability Relationship in Aqueous Colloids of Latex Particles and Gemini Surfactants.

ABSTRACT: The influence of gemini surfactants (GSs) on the charging and aggregation features of anionic sulfate modified latex (SL) particles was investigated by light scattering techniques in aqueous dispersions. The GSs of short alkyl chains (2-4-2 and 4-4-4) resembled simple inert salts and aggregated the particles by charge screening. The adsorption of GSs of longer alkyl chains (8-4-8, 12-4-12, and 12-6-12) on SL led to charge neutralization and overcharging of the particles, giving rise to destabilization and restabilization of the dispersions, respectively. The comparison of the interfacial behavior of dimeric and the corresponding monomeric surfactants revealed that the former shows a more profound influence on the colloidal stability due to the presence of double positively charged head gro

SUBMITTER: Takacs D 

PROVIDER: S-EPMC9910321 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature