Novel application of sodium manganese oxide in removing acidic gases in ambient conditions.

ABSTRACT: In this study, we have demonstrated the application of sodium manganese oxide for the chemisorption of toxic acidic gases at room temperature. The fabricated alkali ceramic has Na_0.4MnO₂, Na₂Mn₃O₇, and Na_xMnO₂ phases with a surface area of 2.6 m² g^-1. Na-Mn oxide was studied for oxidation of H₂S, SO₂, and NO₂ gases in the concentration range of 100-500 ppm. The material exhibited a high uptake capacity of 7.13, 0.75, and 0.53 mmol g^-1 for H₂S, SO₂, and NO₂ in wet conditions, respectively. The material was reusable when regenerated simply by soaking the spent oxide in a NaOH-H₂O₂ solution. While the H₂S chemisorption process was accompanied by sulfide, sulfur, and sulfate formation, the SO₂ chemisorption process yielded only sulfate ions. The NO₂ chemisorption process was accomplished by its conversion to nitrite and nitrate ions. Thus, the present work is one of the first reports on alkali ceramic utilization for room-temperature mineralization of acidic gases.

SUBMITTER: Gupta NK 

PROVIDER: S-EPMC9911640 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature