Syntheses and structures of ammonium transition-metal dialuminium tris-(phosphate) dihydrates (NH4)MAl4(PO4)3·2H2O (M = Mn and Ni).
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ABSTRACT: The structures of ammonium manganese(II) dialuminium tris-(phosphate) dihydrate, (NH4)MnAl2(PO4)3·2H2O, and ammonium nickel(II) dialuminium tris-(phosphate) dihydrate, (NH4)NiAl2(PO4)3·2H2O, were determined using single-crystal diffraction data. The structures of title compounds are isotypic to cobalt aluminophosphate, (NH4)CoAl2(PO4)3·2H2O (LMU-3) [Panz et al. (1998 ▸). Inorg. Chim. Acta, 269, 73-82], in which a three-dimensional network of vertex-sharing AlO5 and PO4 moieties delineate twelve-membered channels in which ammonium, NH4 +, and transition-metal catio
SUBMITTER: Tokuda M
PROVIDER: S-EPMC9912463 | biostudies-literature | 2023 Jan
REPOSITORIES: biostudies-literature
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