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Crystal structure of barium dinickel(II) iron(III) tris-[orthophosphate(V)], BaNi2Fe(PO4)3.

ABSTRACT: The orthophosphate BaNi2Fe(PO4)3 has been synthesized by a solid-state reaction route and characterized by single-crystal X-ray diffraction and energy-dispersive X-ray spectroscopy. The crystal structure comprises (100) sheets made up of [Ni2O10] dimers that are linked to two PO4 tetra-hedra via common edges and vertices and of linear infinite [010] chains of corner-sharing [FeO6] octa-hedra and [PO4] tetra-hedra. The linkage of the sheets and chains into a framework is accomplished through common vertices of PO4 tetra-hedra and [FeO6] octa-hedra. The framework is perforated by channels in which positionally disordered Ba2+ cations are located.

SUBMITTER: Ouaatta S 

PROVIDER: S-EPMC9912466 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of barium dinickel(II) iron(III) tris-[orthophosphate(V)], BaNi<sub>2</sub>Fe(PO<sub>4</sub>)<sub>3</sub>.

Ouaatta Said S   Bouraima Adam A   Benhsina Elhassan E   Khmiyas Jamal J   Assani Abderrazzak A   Saadi Mohamed M   El Ammari Lahcen L  

Acta crystallographica. Section E, Crystallographic communications 20230117 Pt 2

The orthophosphate BaNi<sub>2</sub>Fe(PO<sub>4</sub>)<sub>3</sub> has been synthesized by a solid-state reaction route and characterized by single-crystal X-ray diffraction and energy-dispersive X-ray spectroscopy. The crystal structure comprises (100) sheets made up of [Ni<sub>2</sub>O<sub>10</sub>] dimers that are linked to two PO<sub>4</sub> tetra-hedra <i>via</i> common edges and vertices and of linear infinite [010] chains of corner-sharing [FeO<sub>6</sub>] octa-hedra and [PO<sub>4</sub>]  ...[more]

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