Influence of Side Chain Interdigitation on Strain and Charge Mobility of Planar Indacenodithiophene Copolymers.

ABSTRACT: Indacenodithiophene (IDT) copolymers are a class of conjugated polymers that have limited long-range order and high hole mobilities, which makes them promising candidates for use in deformable electronic devices. Key to their high hole mobilities is the coplanar monomer repeat units within the backbone. Poly(indacenodithiophene-benzothiadiazole) (PIDT_C16-BT) and poly(indacenodithiophene-thiapyrollodione) (PIDT_C16-TPD_C1) are two IDT copolymers with planar backbones, but they are brittle at low molecular weight and have unsuitably high elastic moduli. Substitution of the hexadecane (C₁₆) side chains of the IDT monomer with isocane (C₂₀) side chains was performed to generate a new BT-containing IDT copolymer: PIDT_C20-BT. Substi

SUBMITTER: Sommerville PJW 

PROVIDER: S-EPMC9912480 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature