Fully Flexible Covalent Organic Frameworks for Fluorescence Sensing 2,4,6-Trinitrophenol and p-Nitrophenol.

ABSTRACT: Nitrophenols are important nitroaromatic compounds, both important environmental pollutants and dangerous explosives, posing a devastating danger and pollution threat to humans. It is vital to detect efficiently trace nitrophenols in the environment. In this contribution, a series of fully flexible cyclotriphosphazene-based COFs (FFCP COFs: HDADE, HBAPB, and HBPDA), prepared with both a flexible knot and flexible linkers of different lengths, were used for sensing 2,4,6-trinitrophenol (TNP) and p-nitrophenol (p-NP) in real time with excellent sensitivity and selectivity. The quenching constants of HDADE by TNP, HBAPB, and HBPDA by p-NP are 6.29 × 10⁴, 2.17 × 10⁵, and 2.48 × 10⁵ L·mol^-1, respectively. The LODs of TNP and p<

SUBMITTER: Zhu H 

PROVIDER: S-EPMC9919289 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature