Polyaromatic Group Embedded Cd(II)-Coordination Polymers for Microwave-Assisted Solvent-Free Strecker-Type Cyanation of Acetals.

ABSTRACT: In this work, two new 1D Cd(II) coordination polymers (CPs), [Cd(L1)(NMF)₂]_n (1) and [Cd(L2)(DMF)(H₂O)₂]_n·n(H₂O) (2), have been synthesized, characterized and employed as catalysts for the microwave-assisted solvent-free Strecker-type cyanation of different acetals. Solvothermal reaction between the pro-ligand, 5-{(pyren-1-ylmethyl)amino}isophthalic acid (H₂L1) or 5-{(anthracen-9-ylmethyl)amino}isophthalic acid (H₂L2), and Cd(NO₃)₂.6H₂O in the presence of NMF or DMF:THF solvent, produces the coordination polymer 1 or 2, respectively. These frameworks were characterized by single-crystal and powder X-ray diffraction analyses, ATR-

SUBMITTER: Karmakar A 

PROVIDER: S-EPMC9919643 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature