CoFe Alloy-Coupled Mo₂C Wrapped by Nitrogen-Doped Carbon as Highly Active Electrocatalysts for Oxygen Reduction/Evolution Reactions.

ABSTRACT: Molybdenum carbide (Mo₂C) with a Pt-like d-band electron structure exhibits certain activities for oxygen reduction and evolution reactions (ORR/OER) in alkaline solutions, but it is questioned due to its poor OER stability. Combining Mo₂C with transition metals alloy is a feasible way to stabilize its electrochemical activity. Herein, CoFe-Prussian blue analogues are used as a precursor to compound with graphitic carbon nitride and Mo⁶⁺ to synthesize FeCo alloy and Mo₂C co-encapsulated N-doped carbon (NG-CoFe/Mo₂C). The morphology of NG-CoFe/Mo₂C (800 °C) shows that CoFe/Mo₂C heterojunctions are well wrapped by N-doped graphitic carbon. Carbon coating not only inhibits growth and agglomeration of Mo₂C/

SUBMITTER: Xie J 

PROVIDER: S-EPMC9920335 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature