Two Novel Schiff Base Manganese Complexes as Bifunctional Electrocatalysts for CO₂ Reduction and Water Oxidation.

ABSTRACT: One mononuclear Mn(III) complex [Mn^IIIL(H₂O)(MeCN)](ClO₄) (1) and one hetero-binuclear complex [(Cu^IILMn^II(H₂O)₃)(Cu^IIL)₂](ClO₄)₂·CH₃OH (2) have been synthesized with the Schiff base ligand (H₂L = N,N'-bis(3-methoxysalicylidene)-1,2-phenylenediamine). Single crystal X-ray structural analysis manifests that the Mn(III) ion in 1 has an octahedral coordination structure, whereas the Mn(II) ion in 2 possesses a trigonal bipyramidal configuration and the Cu(II) ion in 2 is four-coordinated with a square-planar geometry. Electrochimerical catalytic investigation demonstrates that the two compl

SUBMITTER: Zhao X 

PROVIDER: S-EPMC9920694 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature