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Study of Lithium-Extraction Systems Based on Benzo-15-Crown-5 Ether and Alkylimidazolium-Based Ionic Liquid.


ABSTRACT: The extraction of lithium from aqueous solutions of LiNTf2 and LiCl salts using benzo-15-crown-5 ether (B15C5) as an extractant in [C8mim][NTf2] ionic liquid was studied. The transition of the extractant into the aqueous phase and the distribution of Cl- ions during lithium extraction from LiCl solutions were determined. LiNTf2 complexes with B15C5 with different LiNTf2:B15C5 ratios were isolated for the first time and characterized via X-ray diffraction and IR spectroscopy. Differences in the extraction process of LiCl and LiNTf2 were determined via an infrared spectroscopic study of the extraction systems.

SUBMITTER: Bezdomnikov AA 

PROVIDER: S-EPMC9920876 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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Study of Lithium-Extraction Systems Based on Benzo-15-Crown-5 Ether and Alkylimidazolium-Based Ionic Liquid.

Bezdomnikov Alexey A AA   Demina Liudmila I LI   Kuz'mina Lyudmila G LG   Kostikova Galina V GV   Zhilov Valeriy I VI   Tsivadze Aslan Yu AY  

Molecules (Basel, Switzerland) 20230117 3


The extraction of lithium from aqueous solutions of LiNTf<sub>2</sub> and LiCl salts using benzo-15-crown-5 ether (B15C5) as an extractant in [C8mim][NTf<sub>2</sub>] ionic liquid was studied. The transition of the extractant into the aqueous phase and the distribution of Cl<sup>-</sup> ions during lithium extraction from LiCl solutions were determined. LiNTf<sub>2</sub> complexes with B15C5 with different LiNTf<sub>2</sub>:B15C5 ratios were isolated for the first time and characterized via X-ra  ...[more]

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