Tetranuclear Copper(I) and Silver(I) Pyrazolate Adducts with 1,1'-Dimethyl-2,2'-bibenzimidazole: Influence of Structure on Photophysics.

ABSTRACT: A reaction of a cyclic trinuclear copper(I) or silver(I) pyrazolate complex ([MPz]₃, M = Cu, Ag) with 1,1'-dimethyl-2,2'-bibenzimidazole (L) leads to the formation of tetranuclear adducts decorated by one or two molecules of a diimine ligand, depending on the amount of the ligand added (0.75 or 1.5 equivalents). The coordination of two L molecules stabilizes the formation of a practically idealized tetrahedral four-metal core in the case of a copper-containing complex and a distorted tetrahedron in the case of a Ag analog. In contrast, complexes containing one molecule of diimine possess two types of metals, two- and three-coordinated, forming the significantly distorted central M₄ cores. The diimine ligands are twisted in these complexes with dihedral a

SUBMITTER: Yakovlev GB 

PROVIDER: S-EPMC9920877 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature