A New Boron-Rhodamine-Containing Carboxylic Acid as a Sugar Chemosensor.

ABSTRACT: We propose a boron-rhodamine-containing carboxylic acid (BRhoC) substance as a new sugar chemosensor. BRhoC was obtained by the Friedel-Crafts reaction of 4-formylbenzoic acid and N,N-dimethylphenylboronic acid, followed by chloranil oxidation. In an aqueous buffer solution at pH 7.4, BRhoC exhibited an absorption maximum (Abs_max) at 621 nm. Its molar absorption coefficient at Abs_max was calculated to be 1.4 × 10⁵ M^-1 cm^-1, and it exhibited an emission maximum (Em_max) at 644 nm for the excitation at 621 nm. The quantum yield of BRhoC in CH₃OH was calculated to be 0.16. The borinate group of BRhoC reacted with a diol moiety of sugar to form a cyclic ester, which induced a change in the absorbance and fluores

SUBMITTER: Komori Y 

PROVIDER: S-EPMC9921257 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature