Interplay of Anisotropic Exchange Interactions and Single-Ion Anisotropy in Single-Chain Magnets Built from Ru/Os Cyanidometallates(III) and Mn(III) Complex.

ABSTRACT: Two novel 1D heterobimetallic compounds {[Mn^III(SB²⁺)M^III(CN)₆]·4H₂O}_n (SB²⁺ = N,N'-ethylenebis(5-trimethylammoniomethylsalicylideneiminate) based on orbitally degenerate cyanidometallates [Os^III(CN)₆]^3- (1) and [Ru^III(CN)₆]^3- (2) and Mn^III Schiff base complex were synthesized and characterized structurally and magnetically. Their crystal structures consist of electrically neutral, well-isolated chains composed of alternating [M^III(CN)₆]^3- anions and square planar [Mn^III(SB²⁺)]³⁺ cations bridged by cyanide groups. These -ion magnetic anisotropy of Mn

SUBMITTER: Mironov VS 

PROVIDER: S-EPMC9921754 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature