Post-synthetic thiol modification of covalent organic frameworks for mercury(II) removal from water.

ABSTRACT: Various materials have been developed for environmental remediation of mercury ion pollution. Among these materials, covalent organic frameworks (COFs) can efficiently adsorb Hg(II) from water. Herein, two thiol-modified COFs (COF-S-SH and COF-OH-SH) were prepared, through the reaction between 2,5-divinylterephthalaldehyde and 1,3,5-tris-(4-aminophenyl)benzene, followed by post-synthetic modification using bis(2-mercaptoethyl) sulfide and dithiothreitol, respectively. The modified COFs showed excellent Hg(II) adsorption abilities with maximum adsorption capacities of 586.3 and 535.5 mg g^-1 for COF-S-SH and COF-OH-SH, respectively. The prepared materials showed excellent selective absorbability for Hg(II) against multiple cationic metals in water. Unexpectedly, the experimental d

SUBMITTER: Wang W 

PROVIDER: S-EPMC9923162 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature