Luminescence and stability of Tb doped CaF₂ nanoparticles.

ABSTRACT: Luminescence properties of CaF₂:Tb³⁺ nanoparticles were studied in order to investigate the effect of CaF₂ native defects on the photoluminescence dynamics of Tb³⁺ ions. Incorporation of Tb ions into the CaF₂ host was confirmed by X-ray diffraction and X-ray photoelectron spectroscopy. Cross-relaxation energy transfer was observed from the photoluminescence spectra and decay curves upon excitation at 257 nm. However, the unusual long lifetime of the Tb³⁺ ion as well as the decreasing trend of emission lifetime of the ⁵D₃ level suggested the involvement of traps, which were further investigated by using temperature-dependent photoluminescence measurements, thermoluminescence and lifetime measurements at

SUBMITTER: Hasabeldaim EHH 

PROVIDER: S-EPMC9924223 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature