Diphenylacetylene stabilised alkali-metal nickelates: synthesis, structure and catalytic applications.

ABSTRACT: Whilst low-valent nickelates have recently been proposed as intermediates in Ni-catalysed reactions involving polar organometallics, their isolation and characterisation is often challenging due to their high sensitivity and reactivity. Advancing the synthetic, spectroscopic and structural insights of these heterobimetallic systems, here we report a new family of alkyne supported alkali-metal nickelates of the formula Li₄(solv)_n(Ar)₄Ni₂{μ₂:η²,η²-Ph-CC-Ph} (where solv = Et₂O, THF; Ar = Ph, o-Tol, naphthyl, 4-^tBu-C₆H₄) which can be accessed through the combination of Ni(COD)₂, Ph-CC-Ph and the relevant lithium aryl in a 2 : 1 : 4 ratio. De

SUBMITTER: Borys AM 

PROVIDER: S-EPMC9926332 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature