Dataset Information

Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co{(OPPh₂)(EPPh₂)N}₂], E = S, Se, explored by experimental and computational methods.

ABSTRACT: During the last few years, a large number of mononuclear Co(II) complexes of various coordination geometries have been explored as potential single ion magnets (SIMs). In the work presented herein, the Co(II) S = 3/2 tetrahedral [Co{(OPPh₂)(EPPh₂)N}₂], E = S, Se, complexes (abbreviated as CoO2E2), bearing chalcogenated mixed donor-atom imidodiphosphinato ligands, were studied by both experimental and computational techniques. Specifically, direct current (DC) magnetometry provided estimations of their zero-field splitting (zfs) axial (D) and rhombic (E) parameter values, which were more accurately determined by a combination of far-infrared magnetic spectroscopy and high-frequency and -field EPR spectroscopy studies. The latter combination of

SUBMITTER: Ferentinos E

PROVIDER: S-EPMC9926333 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Dataset Information

Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co{(OPPh₂)(EPPh₂)N}₂], E = S, Se, explored by experimental and computational methods.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co{(OPPh2)(EPPh2)N}2], E = S, Se, explored by experimental and computational methods.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co{(OPPh₂)(EPPh₂)N}₂], E = S, Se, explored by experimental and computational methods.