Water Increases the Faradaic Selectivity of Li-Mediated Nitrogen Reduction.

ABSTRACT: The lithium-mediated system catalyzes nitrogen to ammonia under ambient conditions. Herein we discover that trace amount of water as an electrolyte additive-in contrast to prior reports from the literature-can effect a dramatic improvement in the Faradaic selectivity of N₂ reduction to NH₃. We report that an optimal water concentration of 35.9 mM and LiClO₄ salt concentration of 0.8 M allows a Faradaic efficiency up to 27.9 ± 2.5% at ambient pressure. We attribute the increase in Faradaic efficiency to the incorporation of Li₂O in the solid electrolyte interphase, as suggested by our X-ray photoelectron spectroscopy measurements. Our results highlight the extreme sensitivity of lithium-mediated N₂ reduction to small changes in the expe

SUBMITTER: Spry M 

PROVIDER: S-EPMC9926485 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature