Ni-Ion-Chelating Strategy for Mitigating the Deterioration of Li-Ion Batteries with Nickel-Rich Cathodes.

ABSTRACT: Ni-rich cathodes are the most promising candidates for realizing high-energy-density Li-ion batteries. However, the high-valence Ni⁴⁺ ions formed in highly delithiated states are prone to reduction to lower valence states, such as Ni³⁺ and Ni²⁺ , which may cause lattice oxygen loss, cation mixing, and Ni ion dissolution. Further, LiPF₆ , a key salt in commercialized electrolytes, undergoes hydrolysis to produce acidic compounds, which accelerate Ni-ion dissolution and the interfacial deterioration of the Ni-rich cathode. Dissolved Ni ions migrate and deposit on the surface of the graphite anode, causing continuous electrolyte decomposition and threatening battery safety by forming Li dendrites on the anode. Herein, 1,2-bis(diphenylphosphino)ethan

SUBMITTER: Park SY 

PROVIDER: S-EPMC9929120 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature