Nanoscale chemical and structural investigation of solid solution polyelemental transition metal oxide nanoparticles.

ABSTRACT: Although it has been shown that configurational entropy can improve the structural stability in transition metal oxides (TMOs), little is known about the oxidation state of transition metals under random mixing of alloys. Such information is essential in understanding the chemical reactivity and properties of TMOs stabilized by configurational entropy. Herein, utilizing electron energy loss spectroscopy (EELS) technique in an aberration-corrected scanning transmission electron microscope (STEM), we systematically studied the oxidation state of binary (Mn, Fe)₃O₄, ternary (Mn, Fe, Ni)₃O₄, and quinary (Mn, Fe, Ni, Cu, Zn)₃O₄ solid solution polyelemental transition metal oxides (SSP-TMOs) nanoparticles. Our findings show that t

SUBMITTER: Phakatkar AH 

PROVIDER: S-EPMC9929587 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature