Synthesis, Crystal Structures, and Optical and Magnetic Properties of Samarium, Terbium, and Erbium Coordination Entities Containing Mono-Substituted Imine Silsesquioxane Ligands.

ABSTRACT: Mono-substituted cage-like silsesquioxanes of the T₈-type can play the role of potential ligands in the coordination chemistry. In this paper, we report on imine derivatives as ligands for samarium, terbium, and erbium cations and discuss their efficient synthesis, crystal structures, and magnetic and optical properties. X-ray analysis of the lanthanide coordination entities [MCl₃(POSS)₃]·2THF [M = Er³⁺ (3), Tb³⁺ (4), Sm³⁺ (5)] showed that all three compounds crystallize in the same space group with similar lattice parameters. All compounds contain an octahedrally coordinated metal atom, and additionally, 3 and 5 structures are strictly isomorphous. However, surprisingly, there are two diff

SUBMITTER: Wytrych P 

PROVIDER: S-EPMC9930112 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature