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Optimal Integrated Plant for Biodegradable Polymer Production.

ABSTRACT: An integrated facility for the production of biodegradable polymers from biomass residues has been developed. Lignocellulosic residues (sawdust), CO₂, and organic waste such as manure or sludge are the raw materials. Manure and sludge are digested to provide the nutrients needed to grow algae. Algae are used in full to oil and starch production. The oil is transesterified with methanol generated via biogas dry reforming to obtain biodiesel and glycerol. The starch is used together with glycerol and the pretreated sawdust for the production of the biodegradable polymer. A mathematical optimization approach is used to identify the best use of each resource and the optimal operation of the integrated facility for each case. 4732 kt/yr of manure or 4653 kt/yr of sludge was processed to produce 354 kt/yr of biopolymer and 84 Mgal/yr of fatty acid methyl ester, capturing 2.47 kg of CO₂ per kg of biopolymer with production costs of 0.89 and 0.95 $/kg, respectively, and an investment capital of 717 and 712 M$, respectively.

SUBMITTER: Roldan-San Antonio JE

PROVIDER: S-EPMC9930116 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature

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Optimal Integrated Plant for Biodegradable Polymer Production.

Roldán-San Antonio José E JE Martín Mariano M

ACS sustainable chemistry & engineering 20230202 6

An integrated facility for the production of biodegradable polymers from biomass residues has been developed. Lignocellulosic residues (sawdust), CO<sub>2</sub>, and organic waste such as manure or sludge are the raw materials. Manure and sludge are digested to provide the nutrients needed to grow algae. Algae are used in full to oil and starch production. The oil is transesterified with methanol generated via biogas dry reforming to obtain biodiesel and glycerol. The starch is used together wit ...[more]

PMID: 36817411

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Project description:BackgroundWhile thinner struts are associated with improved clinical outcomes in bare-metal stents (BMS), reducing strut thickness may affect drug delivery from drug-eluting stents (DES) and there are limited data comparing otherwise similar thin and thick strut DES. We assessed 2-year outcomes of patients treated with a thin strut (84-88um) cobalt-chromium, biodegradable polymer, Biolimus A9-eluting stent (CoCr-BP-BES) and compared these to patients treated with a stainless steel, biodegradable polymer, Biolimus A9-eluting stent (SS-BP-BES).MethodsIn total, 1257 patients were studied: 400 patients from 12 centres receiving ≥1 CoCr-BP-BES in the prospective Biomatrix Alpha registry underwent prespecified comparison with 857 patients who received ≥1 Biomatrix Flex SS-BP-BES in the LEADERS study (historical control). The primary outcome was major adverse cardiac events (MACE)-cardiac death, myocardial infarction (MI), or clinically driven target vessel revascularization (cd-TVR). Propensity analysis was used to adjust for differences in baseline variables and a landmark analysis at day-3 to account for differences in periprocedural MI definitions.ResultsMACE at 2 years occurred in 6.65% CoCr-BP-BES versus 13.23% SS-BP-BES groups (unadjusted HR 0.48 [0.31-0.73]; P=0.0005). Following propensity analysis, 2-year adjusted MACE rates were 7.4% versus 13.3% (HR 0.53 [0.35-0.79]; P=0.004). Definite or probable stent thrombosis, adjudicated using identical criteria in both studies, occurred less frequently with CoCr-BP-BES (1.12% vs. 3.22%; adjusted HR 0.32 [0.11-0.9]; P=0.034). In day-3 landmark analysis, the difference in 2-year MACE was no longer significant but there was a lower patient-orientated composite endpoint (11.7% vs. 18.4%; HR 0.6 [0.43-0.83]; P=0.006) and a trend to lower target vessel failure (5.8% vs. 9.1%; HR 0.63 [0.4-1.00]; P=0.078).ConclusionAt 2-year follow-up, propensity-adjusted analysis showed the thin strut (84-88um) Biomatrix Alpha CoCr-BP-BES was associated with improved clinical outcomes compared with the thicker strut (114-120um) Biomatrix Flex SS-BP-BES.

Dataset Information

Optimal Integrated Plant for Biodegradable Polymer Production.

Publications

Optimal Integrated Plant for Biodegradable Polymer Production.

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