Lithium, Tin(II), and Zinc Amino-Boryloxy Complexes: Synthesis and Characterization.

ABSTRACT: Analogous to the ubiquitous alkoxide ligand, metal boroxide and boryloxy complexes are an underexplored class of hard anionic O^- ligand. A new series of amine-stabilized Li, Sn(II), and Zn boryloxy complexes, comprising electron-rich tetrahedral boron centers have been synthesized and characterized. All complexes have been characterized by one-dimensional (1D), two-dimensional (2D), and DOSY NMR, which are consistent with the solid-state structures unambiguously determined via single-crystal X-ray diffraction. Electron-rich μ²- (Sn and Zn) and μ³- (Li) boryloxy binding modes are observed. Compounds 6-9 are the first complexes of this class, with the chelating bis- and tris-phenol ligands providing a scaffold that can be easily functionalized a

SUBMITTER: Straiton AJ 

PROVIDER: S-EPMC9930121 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature