A nickel(ii)-based one-dimensional organic-inorganic halide perovskite ferroelectric with the highest Curie temperature.

ABSTRACT: Organic-inorganic halide perovskites (OIHPs) are very eye-catching due to their chemical tunability and rich physical properties such as ferroelectricity, magnetism, photovoltaic properties and photoluminescence. However, no nickel-based OIHP ferroelectrics have been reported so far. Here, we designed an ABX₃ OIHP ferroelectric (3-pyrrolinium)NiCl₃, where the 3-pyrrolinium cations are located on the voids surrounded by one-dimensional chains composed of NiCl₆-face-sharing octahedra via hydrogen bonding interactions. Such a unique structure enables the (3-pyrrolinium)NiCl₃ with a high spontaneous polarization (P _s) of 5.8 μC cm^-2 and a high Curie temperature (T _c) of 428 K, realizing dramatic e

SUBMITTER: Ni HF 

PROVIDER: S-EPMC9930933 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature