Photocatalytic cyclohexane oxidation and epoxidation using hedgehog particles.

ABSTRACT: Inorganic particles are effective photocatalysts for the liquid-state production of organic precursors and monomers at ambient conditions. However, poor colloidal stability of inorganic micro- and nanoparticles in low-polarity solvents limits their utilization as heterogeneous catalysts and coating them with surfactants drastically reduces their catalytic activity. Here we show that effective photo-oxidation of liquid cyclohexane (CH) is possible using spiky particles from metal oxides with hierarchical structure combining micro- and nanoscale structural features engineered for enhanced dispersibility in CH. Nanoscale ZnO spikes are assembled radially on α-Fe₂O₃ microcube cores to produce complex 'hedgehog' particles (HPs). The 'halo' of stiff spikes reduces van der W

SUBMITTER: Montjoy DG 

PROVIDER: S-EPMC9932155 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature