Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.

ABSTRACT: The synthesis and characterisation of the rhodium(III) dinitrogen complex [Rh(2,2'-biphenyl)(CxP₂)(N₂)]⁺ are described, where CxP₂ is a trans-spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle.

SUBMITTER: Emerson-King J 

PROVIDER: S-EPMC9933454 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature