Real-time observation of the buildup of polaron in α-FAPbI₃.

ABSTRACT: The formation of polaron, i.e., the strong coupling process between the carrier and lattice, is considered to play a crucial role in benefiting the photoelectric performance of hybrid organic-inorganic halide perovskites. However, direct observation of the dynamical formation of polarons occurring at time scales within hundreds of femtoseconds remains a technical challenge. Here, by terahertz emission spectroscopy, we demonstrate the real-time observation of polaron formation process in FAPbI₃ films. Two different polaron resonances interpreted with the anharmonic coupling emission model have been studied: P1 at ~1 THz relates to the inorganic sublattice vibration mode and the P2 at ~0.4 THz peak relates to the FA⁺ cation rotation mode. Moreover, P2 could be further s

SUBMITTER: Yue X 

PROVIDER: S-EPMC9938110 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature